Which pair of metals does not dissolve in nitric acid?

In the nitrogen family,the $H-M-H$ bond angle in the hydrides $MH_3$ gradually becomes closer to $90^o$ on going from $N$ to $Sb$. This shows that gradually:

Phosphine is prepared by the reaction of $P_4$ with which of the following?

In a cyclotrimetaphosphoric acid molecule,how many single and double bonds are present?

How many of the following reactions will form $PH_3$ gas?
$(1)$ $Ca_3P_2 + H_2O \to$
$(2)$ $H_3PO_3 \xrightarrow{\Delta} $
$(3)$ $P_4 + NaOH \to$
$(4)$ $H_3PO_4 \xrightarrow{\Delta} $
$(5)$ $HNO_3 + P_4O_{10} \to$
$(6)$ $P_4 + HNO_3 \to$

How is ammonia manufactured industrially?